ISO 9001:2015

INTERNATIONAL JOURNAL OF GLOBAL RESEARCH INNOVATIONS & TECHNOLOGY (IJGRIT) [ Vol. 4 | No. 2(II) | April - June, 2026 ]

Spectroscopic Study of Al Doped Zinc Oxide (AZNO) Thin Films for Optoelectronic Devices

Dr. Shital Prasad & Vandana Agrawal

Recently, large band gap semiconductor (ZnO) is among the largest studied material because of a wide range of applications in photodetectors, light emitting diode, blue and ultraviolet laser diodes, transparent conductive oxides (TCOs), transparent field effect transistors, gas sensors, solar cell and dilute magnetic semiconductors (DMSs). This paper reports 1 at% Al doped ZnO (AZNO) thin films prepared by sol-gel spin coating method at 1000rpm to 6000rpm spin coating speeds. The sol was prepared from zinc acetate dehydrate, 2-methoxyethanol and mono-ethanolamine as precursor, solvent and stabilizer respectively. Aluminium chloride hexahydrate was used for doping of Al. The effect of spin coating speed on absorbance, transmission, Raman shift and fluorescence spectra of Aldoped ZnO thin films is studied in this paper. The absorbance of thin films decreases corresponding to increase in spinning speed. The transmittance of all thin films in the range 400nm to 700nm is greater than 90%. Raman and fluorescence spectra of thin films show that the intensity of both spectra decreases with increase in the spin coating speed.

Prasad, S. & Agrawal, V. (2026). Spectroscopic Study of Al Doped Zinc Oxide (AZNO) Thin Films for Optoelectronic Devices. International Journal of Global Research Innovations & Technology, 04(02(II)), 10–18. https://doi.org/10.62823/IJGRIT/4.2(II).9084
  1. Kelly, P.J. and Arnell, R.D., “Magnetron sputtering: A review of recent developments and applications”, Vacuum, Vol. 56, pp. 159–172, 2000.
  2. Minami, T., “Present status of transparent conducting oxide thin-film development for indium-tin- oxide (ITO) substitutes”, Thin Solid Films, Vol. 516, pp. 5822–5828, 2008.
  3. Ellmer, K., Klein, A. and Rech, B., Transparent Conductive Zinc Oxide, 1st. ed., Springer, 2007.
  4.  Lin, Y.C., Le, Q.K., Lai, L.W., Liao, R.M., Jeng, M.S. and Liu, D.S., “Optimizing the organic/inorganic barrier structure for flexible plastic substrate encapsulation”, International Journal of Engineering and Technology Innovation, Vol. 2, pp. 184–194, 2012.
  5. Minami, T., Sato, H., Nanto, H. and Takata, S., “Heat treatment in hydrogen gas and plasma for transparent conducting oxide films such as ZnO, SnO2, and indium tin oxide”, Thin Solid Films, Vol. 176, pp. 277–282, 1989.
  6. Minami, T., Oohashi, K. and Takata, S., “Preparations of ZnO:A1 transparent conducting films by d.c. magnetron sputtering”, Thin Solid Films, Vol. 194, pp. 721–729, 1990.
  7. Szyszka, B., “Transparent and conductive aluminum doped zinc oxide films prepared by mid-frequency reactive magnetron sputtering”, Thin Solid Films, Vol. 351, pp. 164–169, 1999.
  8. Ali, F., Abdul, R., Suganthi, D., Sanjeeviraja, C. and Swaninathan, V., Efeect of Annealing on Structural and Optical Properties of ZnO Thin Fils by Sol-Gel Technique, Chalcogenide Letters, , (2011), 8, 511-519.
  9. Ajadi, D. A., Agboola S. M., Adedokun, O., Effect of Spin Coating Speed on Some Optical Properties of ZnO Thin Films, J. of Mat. Sci. and Chem. Engg., (2016), 4, 1-6.
  10. Li J, Xu J, Xu Q, Fang G, Preparation and Characterization of Al doped ZnO thin films by sol gel process, J. Alloys and Compounds 2012: 542-151-6
  11. Zi-NengNg, Kah-YoongChan, Cheng-YangLow, Sharul Ashikin Kamaruddin, Mohd Zainizan Sahdan, “Al and Ga doped ZnO films prepared by a sol–gel spin coating technique”, Ceramics International,  41(1)  2015 S254-S258
  12. M. U. Shahid, K. M. Deen, A. Ahmad, M. A. Akram, M. Aslam, W. Akhtar, “Formation of Al-doped ZnO thin films on glass by sol–gel process and characterization”, Applied Nanoscienc, 6(2) (2016) 235–241
  13. K. Dev Arun Kumar, S. Valanarasu, A. Kathalingam, V. Ganesh, Mohd. Shkir, S. AlFaify, “Effect of solvents on sol–gel spin-coated nanostructured Al-doped ZnO thin films: a film for key optoelectronic applications”, Applied Physics A, (2017) 123:801
  14. R.Kraya, J.Baskar, A.Arceo, H.E.Katz, N.Thakor, “Ultra-low resistivity aluminum doped ZnO thin films on flexible substrates using sol-gel solution deposition”, Thin Solid Films, 664( 31) (2018) 41-45
  15. Bouacheria, M. A., A. Djelloul, M. Adnane, Y. Larbah, and L. Benharrat. "Characterization of pure and Al doped ZnO thin films prepared by sol gel method for solar cell applications." Journal of Inorganic and Organometallic Polymers and Materials 32, no. 7 (2022): 2737-2747.
  16. Koralli, Panagiota, Songül Fiat Varol, George Mousdis, Dionysios E. Mouzakis, Ziya Merdan, and Michael Kompitsas. "Comparative studies of undoped/Al-doped/In-doped ZnO transparent conducting oxide thin films in optoelectronic applications." Chemosensors 10, no. 5 (2022): 162.
  17. Rekkache, Hadjer, Samiha Mezrag, Mamoun Fellah, Dikra Bouras, Lakhdar Bechiri, NourreddineBenslim, Ahlem Guesmi, and Lotfi Khezami. "Characterization of RF magnetron sputtered pure and aluminum-doped zinc oxide thin films for optoelectronic applications." Journal of Materials Science: Materials in Electronics 36, no. 16 (2025): 934.
  18. Deng Xr, Deng H, Wei M, Chen JJ, Preparation of highly transparent conductive Al doped ZnO thin films and annealing effects on properties, j. Mater. Sci. Mater. Electron 2012; 23: 413-7.
  19. Ding JJ, Chen HX, Ma Sy, Structural and photoluminescence properties of Al doped ZnO films deposited on Si substrate, Physica E2010; 42: 1861-4.
  20. Wang T, Liu Y, Fang Q, Wu M, Sun X, Lu F, Low temperature synthesis wide optical band gap Al and (Al, Na) co-doped ZnO thin films, Appl. Surf. Sci. 2011; 257: 2341-5.

DOI:

Article DOI: 10.62823/IJGRIT/4.2(II).9084

DOI URL: https://doi.org/10.62823/IJGRIT/4.2(II).9084


Download Full Paper:

Download